Thermal fluctuations in metastable fluids

Metastable conduction states in Mo2S3: Conductivity fluctuations.

Dynamical signatures of freezing: stable fluids, metastable fluids, and crystals.

Mean squared displacements and velocity auto correlation functions are calculated using molecular dynamics for hard spheres under a range of conditions (i) for the equilibrium fluid below freezing; (ii) for the metastable fluid above freezing; and (iii) for the hard sphere crystal, both in the metastable region between freezing and melting, and in the stable region above melting. In addition, s...

Nonlinear viscoelasticity of metastable complex fluids

– Many metastable complex fluids such as colloidal glasses and gels show distinct nonlinear viscoelasticity with increasing oscillatory-strain amplitude; the storage modulus decreases monotonically as the strain amplitude increases whereas the loss modulus has a distinct peak before it decreases at larger strains. We present a qualitative argument to explain this ubiquitous behavior and use mod...

Fluctuations in fluids in thermal nonequilibrium states below the convective Rayleigh-Bénard instability

Starting from the linearized fluctuating Boussinesq equations we derive an expression for the structure factor of fluids in stationary convection-free thermal nonequilibrium states, taking into account both gravity and finite-size effects. It is demonstrated how the combined effects of gravity and finite size causes the structure factor to go through a maximum value as a function of the wave nu...

Modelling thermal fluctuations in non-ideal fluids with the lattice Boltzmann method.

Recently, we proposed a theoretical framework to include thermal fluctuations into the Lattice Boltzmann (LB) method for non-ideal fluids. Here, we apply a variant thereof to a certain class of force-based non-ideal fluid LB models. We find that ideal-gas-like noise is an exact result of the fluctuation-dissipation theorem in the hydrodynamic regime. It is shown that satisfactory equilibration ...